A total synthesis of the sesquiterpene, (+)-taylorione 1 starting from (+)-2-carene is described; the key synthetic transformation is achieved in high yield by application of developed Pauson–Khand reaction techniques for gaseous olefins.
C. Johnstone, W. J. Kerr and U. Lange, J. Chem. Soc., Chem. Commun., 1995, 457 DOI: 10.1039/C39950000457
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