The Norrish type I cleavage overwhelms the type II cleavage in the photolysis of α-alkylcycloalkanones bearing an SiMe3, SiMe2Ph, SiMePh2, or SiPh3 group at the β position, of which the quantum yields are often greater than those of the non-silylated cycloalkanones.
J. R. Hwu, B. Chen, L. W. Huang and T. Yang, J. Chem. Soc., Chem. Commun., 1995, 299 DOI: 10.1039/C39950000299
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