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Issue 10, 1995
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Stereocontrol in cyclisation of dioxolanyl radicals

Abstract

Appropriate nitrate esters are cleaved under photolytic or thermal (tributyltin radical) conditions to yield dioxolanyl radicals which undergo stereoselective cyclisation to heterocyclic products. The X-ray crystallographic structures for compounds 30a and 35 are reported.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1995, 1281-1294
Article type
Paper

Stereocontrol in cyclisation of dioxolanyl radicals

A. S. Batsanov, M. J. Begley, R. J. Fletcher, J. A. Murphy and M. S. Sherburn, J. Chem. Soc., Perkin Trans. 1, 1995, 1281
DOI: 10.1039/P19950001281

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