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Issue 18, 1995
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Synthesis and characterisation of iridium carbonyl fluorides

Abstract

Tetrairidium dodecacarbonyl reacted with XeF2 in anhydrous HF solution at low temperatures via sequential fluorination yielding initially fac- and mer-[IrF3(CO)3] and finally IrF5. The novel 18-electron iridium carbonyl fluorides have been characterised by a combination of IR spectroscopy, 13C, 13C-{19F} and 19F NMR spectroscopies and extended X-ray absorption fine structure spectroscopy studies in HF solution.

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Article information


J. Chem. Soc., Dalton Trans., 1995, 2945-2948
Article type
Paper

Synthesis and characterisation of iridium carbonyl fluorides

S. A. Brewer, A. K. Brisdon, J. H. Holloway, E. G. Hope, L. A. Peck and P. G. Watson, J. Chem. Soc., Dalton Trans., 1995, 2945
DOI: 10.1039/DT9950002945

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