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Issue 7, 1995
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The synthesis and characterisation of [Ru6C(CO)1531 : η2 : η2-C16H162-O)]: an intermediate in the formation of the carbido-cluster [Ru6C(CO)1432 : η2 : η2-C16H16)]

Abstract

The complex Ru6C(CO)1531 : η2 : η2-C16H162-O)1 is isolated and fully characterised in solution and in the solid-state by a single crystal X-ray diffraction analysis: it constitutes a rare example of a molecular system containing both the carbido- and oxo-ligand of a cleaved carbonyl group which are trapped within a metal cluster framework; on heating 1 undergoes quantitative conversion to the carbido-cluster, Ru6C(CO)1432 : η2 : η2-C16H16)2, with the elimination of CO2.

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Article type: Paper
DOI: 10.1039/C39950000771
J. Chem. Soc., Chem. Commun., 1995, 771-772

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    The synthesis and characterisation of [Ru6C(CO)1531 : η2 : η2-C16H162-O)]: an intermediate in the formation of the carbido-cluster [Ru6C(CO)1432 : η2 : η2-C16H16)]

    P. J. Dyson, B. F. G. Johnson, C. M. Martin, D. Braga and F. Grepioni, J. Chem. Soc., Chem. Commun., 1995, 771
    DOI: 10.1039/C39950000771

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