Ketenimines 1, react with arene-sulfanyl and -selanyl chlorides to give the imidoyl chlorides 3 that either yield the substituted amides 4 upon solvolysis in aqueous acetone, or the C-sulfanyl- and C-selanyl-ketenimines 5 by dehydrochlorination with triethylamine.
D. G. McCarthy, P. O. McCutcheon and D. P. Sheehan, J. Chem. Soc., Perkin Trans. 1, 1994, 2899 DOI: 10.1039/P19940002899
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