Allylic alcohols bearing a diphenylphosphinoyl group undergo asymmetric epoxidation with excellent enantioselectivity, and can undergo kinetic resolution with good diastereoselectivity, with the diphenylphosphinoyl group exerting an anti-directing effect on the epoxidation.
J. Clayden and S. Warren, J. Chem. Soc., Perkin Trans. 1, 1994, 2811 DOI: 10.1039/P19940002811
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