SCHEDULED MAINTENANCE
A new electrophilic alaninol synthon, (S)-4-(4′-tolylsulfonyloxymethyl)oxazolidin-2-one, derived from serine, undergoes nucleophilic displacements with Gilman cuprates and/or Grignard/CuX reagents in high yield to provide (R)-4-substituted oxazolidinones.
M. P. Sibi, D. Rutherford and R. Sharma, J. Chem. Soc., Perkin Trans. 1, 1994, 1675 DOI: 10.1039/P19940001675
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