Pulse labelling experiments using 60Co2+ and [methyl-13C, 14C]-S-adenosyl-L-methionine have established that in the anaerobic organism Propionibacterium shermanii cobalt is inserted into the macrocycle after the second and before the fourth C-methylation step.
S. Balachandran, R. A. Vishwakarma, S. M. Monaghan, A. Prelle, N. P. J. Stamford, F. J. Leeper and A. R. Battersby, J. Chem. Soc., Perkin Trans. 1, 1994, 487 DOI: 10.1039/P19940000487
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