Information on the potential-energy surfaces of the ground and 1σσ* excited states of oligosilane chains, collected from experimental and theoretical sources, is discussed in terms of electronic structure and the mechanisms of bond and excitation delocalization.
H. S. Plitt, J. W. Downing, M. K. Raymond, V. Balaji and J. Michl, J. Chem. Soc., Faraday Trans., 1994, 90, 1653 DOI: 10.1039/FT9949001653
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