The complex [NH4]2[WVIO2{O2CC(S)Ph2}2] is the first example of a non-dithiolene tungsten complex capable of oxidising benzoin to benzil in methanol; the reduced complex product formed, presumably a monomeric WVIO species, was reoxidised with nitrate ions, regenerating the starting WVIO2 complex which then acts as a true homogeneous catalyst.
A. Cervilla, E. Llopis, A. Ribera, A. Doménech and E. Sinn, J. Chem. Soc., Dalton Trans., 1994, 3511 DOI: 10.1039/DT9940003511
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