Issue 17, 1994

Synthesis, photophysics and electrochemistry of a novel luminescent platinum(II) sulfido complex. Crystal structure of [Pt2(µ-S)(µ-dppm)(dppm)2]2+(dppm = Ph2PCH2PPh2)

Abstract

The novel luminescent dimeric complex [Pt2(µ-S)(µ-dppm)(dppm)2]2+ has been isolated from the reaction of PtCl2, dppm (Ph2PCH2PPh2) and NaSH in the presence of triethylamine in MeCN; the crystal structure revealed dppm ligands displaying two different modes of co-ordination, bridging and chelating.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 2587-2588

Synthesis, photophysics and electrochemistry of a novel luminescent platinum(II) sulfido complex. Crystal structure of [Pt2(µ-S)(µ-dppm)(dppm)2]2+(dppm = Ph2PCH2PPh2)

V. W. Yam, P. K. Yeung and K. Cheung, J. Chem. Soc., Dalton Trans., 1994, 2587 DOI: 10.1039/DT9940002587

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