Issue 17, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, photophysical properties and crystal structure of tetra-n-butylammonium bis(maleonitriledithiolato)-nitridoosmate(VI)

Wa-Hung Leung,   Man-Ching Wu,   Chi-Ming Che,   Wing-Tak Wong  and  Kwok-Fai Chin  

Abstract

Treatment of [NBun][OsNCl4] with 2 equivalents of Na2(mnt)(mnt = maleonitriledithiolate) gave [NBun4][OsN(mnt)2]1 in good yield. The structure of 1 has been confirmed by an X-ray diffraction analysis, Os[triple bond, length half m-dash]N being 1.639(8)Å. The complex shows emission from the 3[(dxy)(dπ*)] excited state.

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Article information

DOI
https://doi.org/10.1039/DT9940002519
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 2519-2521

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Synthesis, photophysical properties and crystal structure of tetra-n-butylammonium bis(maleonitriledithiolato)-nitridoosmate(VI)

W. Leung, M. Wu, C. Che, W. Wong and K. Chin, J. Chem. Soc., Dalton Trans., 1994, 2519 DOI: 10.1039/DT9940002519

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