Issue 11, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Chiral induction in the reduction of [Co(glyO)(ox)2]2– by [Co(phen)3]2+(glyO = glycinate, ox = oxalate, phen = 1,10-phenanthroline)

Robert M. L. Warren,   Akira Tatehata  and  A. Graham Lappin  

Abstract

Oxidation of [Co(phen)3]2+(phen = 1,10-phenanthroline) by [Co(glyO)(ox)2]2–(glyO = glycinate, ox = oxalate) has been found to be an outer-sphere reaction with a second-order rate constant of 0.14 dm3 mol–1 s–1 at 25 °C and 0.01 mol dm–3 ionic strength. Chiral induction amounting to a 37% enantiomeric excess of the Δ isomer in the [Co(phen)3]3+ product was detected when Δ-[Co(glyO)(ox)2]2– was used as oxidant.

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Article information

DOI
https://doi.org/10.1039/DT9940001655
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 1655-1657

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Chiral induction in the reduction of [Co(glyO)(ox)2]2– by [Co(phen)3]2+(glyO = glycinate, ox = oxalate, phen = 1,10-phenanthroline)

R. M. L. Warren, A. Tatehata and A. G. Lappin, J. Chem. Soc., Dalton Trans., 1994, 1655 DOI: 10.1039/DT9940001655

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