The oxidative fluorination of [Os3(CO)12] with XeF2 in anhydrous HF afforded, in solution, cis-[Os(CO)4F2] as the major product with [Os(CO)5F]+, [Os2(CO)7F4] and [Os2(CO)8F3]+ as minor products, all of which have been characterised by 13C, 19F and 13C-{19F} NMR spectroscopies. Removal of the HF solvent in vacuoyielded the tetrameric [{Os(CO)3F2}4].
S. A. Brewer, J. H. Holloway and E. G. Hope, J. Chem. Soc., Dalton Trans., 1994, 1067 DOI: 10.1039/DT9940001067
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