N,N-Dibutyl-N′-naphthoylthiourea (HL1) reacted with [PtCl4]2– to yield a mixture of cis-(85%) and trans-[PtL12](15%); the crystal structure of the latter has been determined and represents the first example of trans chelation of N,N-dialkyl-N′-acylthiourea ligands.
K. R. Koch, J. du Toit, M. R. Caira and C. Sacht, J. Chem. Soc., Dalton Trans., 1994, 785 DOI: 10.1039/DT9940000785
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