Issue 24, 1994

Allylic rearrangements during the rhodium-catalysed reactions of 2-allyloxybenzylamines and 2-(N-allyl-N-benzylamino)benzylamine

Abstract

Reactions of 2-allyloxybenzylamines with H2/CO in the presence of rhodium catalysts give 1,3-benzoxazines via a reaction which involves allylic cleavage and carbonylation as demonstrated by crossover experiments.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2763-2763

Allylic rearrangements during the rhodium-catalysed reactions of 2-allyloxybenzylamines and 2-(N-allyl-N-benzylamino)benzylamine

E. M. Campl, W. R. Jackson, Q. J. McCubbin and A. E. Trnacek, J. Chem. Soc., Chem. Commun., 1994, 2763 DOI: 10.1039/C39940002763

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