Sulfur-substituted allylcopper species, generated by a novel reduction reaction of ketene dithoacetals bearing a chlorine atom at an allylic position using organocuprate, react with aldehyde, ketone, chlorotrimethylsilane, enone, oxirane and ester to afford the corresponding allylated products.
M. Hojo, H. Harada, C. Murakami and A. Hosomi, J. Chem. Soc., Chem. Commun., 1994, 2687 DOI: 10.1039/C39940002687
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