Catalase activity of manganese porphyrin dimers linked by various spacer molecules reveals a remarkable relationship between Mn–Mn separation and arrangement; the highest turnover rate is observed when the two Mn ions can cooperatively interact with a H2O2 molecule in the catalyst cavity.
Y. Naruta and M. Sasayama, J. Chem. Soc., Chem. Commun., 1994, 2667 DOI: 10.1039/C39940002667
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