The reactions of [Mo2(µ-S2)2(S2CNEt2)4](BF4)2 and MoO(S2)(S2CNR2)2 with dimethyl acetylenedicarboxylate result in the formation of orange and green heterometallacyclic complexes containing the novel organosulfur 2-sulfanylethylthiomethylidene (N,N-dialkyl) ammoniumato-C,S,S′ and 2,3-µ-1,3-disulfanylprop-2-enylidene (N,N-dialkyl)-ammoniumato-S,S′ ligands.
C. G. Young, X. F. Yan, B. L. Fox and E. R. T. Tiekink, J. Chem. Soc., Chem. Commun., 1994, 2579 DOI: 10.1039/C39940002579
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