It is demonstrated for the first time that α-halogenoalkyllithium reagents can be utilized for ring opening alkylation of various oxiranes, oxtane and oxolane (THF) in the presence of boron trifluoride–diethyl ether at low temperatures.
T. Imai, S. Nishida and T. Tsuji, J. Chem. Soc., Chem. Commun., 1994, 2353 DOI: 10.1039/C39940002353
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