Reaction of bis[8-(dimethylamino)naphthyl]dihydrosilane with iodine gives 2[L2SiH]+I82–{L =[8-(dimethylamino)naphthyl]}; the X-ray crystal structure determination shows a slightly distorted trigonal bipyramid around the silicon atom with apical NMe2 ligands and short Si–N distances [2.06 and 2.08(1)Å].
C. Brelière, F. Carré, R. Corriu and M. W. C. Man, J. Chem. Soc., Chem. Commun., 1994, 2333 DOI: 10.1039/C39940002333
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