The first copper(I) complex with aminopyrene [Cu(apyr)3]ClO4·MeOH is synthesized and characterized crystallographically; the most remarkable feature of the compound is its 2D structure connected through intra- and inter-molecular stacking of the aromatic rings.
M. Munakata, J. Dai, M. Maekawa, K. Takayoshi and J. Fukui, J. Chem. Soc., Chem. Commun., 1994, 2331 DOI: 10.1039/C39940002331
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