Photocurrent–voltage characteristic of the junction formed between a porous nanocrystalline TiO2 film and an electrolyte is shown to be governed by the kinetics of the interfacial hole transfer to the oxidizable species in the solution.
A. Wahl, M. Ulmann, A. Carroy and J. Augustynski, J. Chem. Soc., Chem. Commun., 1994, 2277 DOI: 10.1039/C39940002277
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