The ligands CO, P(OR)3, and X–(X = Cl, Br, I) add selectively to the Re Pt3 sites in the coordinatively unsaturated clusters [Pt3{Re(CO)3}(µ-dppm)3]+ and [Pt3{ReO3}(µ-dppm)3]+ respectively, dppm = Ph2PCH2PPh2: the selectivity thus displays a remarkable dependency on the oxidation state of rhenium.
J. Xiao, L. Hao, R. J. Puddephatt, L. Manojlović-Muir, K. W. Muir and A. A. Torabi, J. Chem. Soc., Chem. Commun., 1994, 2221 DOI: 10.1039/C39940002221
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