Issue 18, 1994

Synthesis, crystal and molecular structure of the first metal complex [Pt(PPh3)22-As[triple bond, length half m-dash]C(C6H2But3)}] derived from an arsaalkyne

Abstract

Treatment of [Pt(PPh3)2(C2H4)] with As[triple bond, length half m-dash]C(C6H2But3) affords the title compound, the X-ray crystal structure of which shows the arsaalkyne ligand to be η2-ligated; the X-ray crystal structure of the parent arsaalkyne is also reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2061-2062

Synthesis, crystal and molecular structure of the first metal complex [Pt(PPh3)22-As[triple bond, length half m-dash]C(C6H2But3)}] derived from an arsaalkyne

P. B. Hitchcock, C. Jones and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1994, 2061 DOI: 10.1039/C39940002061

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