Issue 17, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Macropolyhedral boron-containing cluster chemistry. A reductive trimerisation of MeNC to give an imidazole-based carbene stabilized by coordination to boron in an eighteen-vertex cluster compound

Tomáš Jelínek,   John D. Kennedy,   Bohumil Štíbr  and  Mark Thornton-Pett  

Abstract

Reaction of MeNC with anti-B18H22 yields 7-{(MeNH)C3N2HMe2}-anti-B18H20, in which a reductive trimerisation of MeNC via a cluster redox process gives an unusual imidazole-based carbene, {(MeNH)C3N2HMe2}, that is stabilized by coordination to the {anti-B18} macropolyhedral cluster.1

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Article information

DOI
https://doi.org/10.1039/C39940001999
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1999-2000

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Macropolyhedral boron-containing cluster chemistry. A reductive trimerisation of MeNC to give an imidazole-based carbene stabilized by coordination to boron in an eighteen-vertex cluster compound

T. Jelínek, J. D. Kennedy, B. Štíbr and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1994, 1999 DOI: 10.1039/C39940001999

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