The first total synthesis of Furoscrobiculin B is accomplished by construction of the azuleno[6,7-c]furan ring system by base catalysed pinacol-type rearrangement of isonaphthofuran derivative, prepared from suitably functionalized hydrobenzofuran by use of the Furan Ring Transfer (FRT) reaction.
T. Ogino, C. Kurihara, Y. Baba and K. Kanematsu, J. Chem. Soc., Chem. Commun., 1994, 1979 DOI: 10.1039/C39940001979
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