A one-dimensional polymer {[Cd2(µ-bpe)3](NO3)4}n[1, bpe = 1,2-bis(4-pyridyl)ethane] is prepared; its structure is strikingly characterised by heptacoordinate CdII ions as well as by a unique main framework, i.e. two bpe units bridge two CdII ions giving a cyclic closed structure which is linked to the next one by another bpe unit.
M. Fujita, Y. J. Kwon, M. Miyazawa and K. Ogura, J. Chem. Soc., Chem. Commun., 1994, 1977 DOI: 10.1039/C39940001977
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