Issue 16, 1994

(4S,8S)-4,8-bis(diphenylmethyl)-1,5,7-triazabicyclo[4,4,0]dec-5-ene; a hindered, chiral, bicyclic guanidine base with effective C2-symmetry

Abstract

The title compound 5 is prepared from L-methionine and investigated by computational, NMR spectroscopic and other techniques; the results indicate that the N/NH groups of 5 and its conjugate acid occupy hindered, chiral environments due to the disposition of the bulky diphenylmethyl substituents.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1875-1876

(4S,8S)-4,8-bis(diphenylmethyl)-1,5,7-triazabicyclo[4,4,0]dec-5-ene; a hindered, chiral, bicyclic guanidine base with effective C2-symmetry

P. H. Boyle, A. P. Davis, K. J. Dempsey and G. D. Hosken, J. Chem. Soc., Chem. Commun., 1994, 1875 DOI: 10.1039/C39940001875

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