Issue 15, 1994

Facile synthesis of highly substituted Pd–η3-allyl complexes containing nitrogen ligands

Abstract

The first examples of quantitative migratory insertion of allene, 1,1-dimethylallene (DMA) and tetramethylallene (TMA) into alkyl and acyl palladium complexes containing bidentate and terdentate nitrogen ligands are presented; very stable palladium η3-allyl compounds containing 2,2′-bipyridine and 2-(2-{[(6′-methyl-2-pyridyl)methylene]amino}ethyl)-pyridine and an exceptional η1-allyl palladium complex containing terpy have been obtained.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1817-1819

Facile synthesis of highly substituted Pd–η3-allyl complexes containing nitrogen ligands

R. E. Rülke, D. Kliphuis, C. J. Elsevier, J. Fraanje, K. Goubitz, P. W. N. M. van Leeuwen and K. Vrieze, J. Chem. Soc., Chem. Commun., 1994, 1817 DOI: 10.1039/C39940001817

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