In a reaction relevant to environmetally important processes carried out by copper-containing enzymes and heterogeneous catalysts, copper(I) complexes of 1,4,7-triisopropyl-1,4,7-triazacyclononane dissolved in alcohols (e.g. benzyl alcohol) efficiently promote the reduction of NO to N2O by the solvent at room temperature, yielding the respective carbonyl compounds (e.g. benzaldehyde).
S. Mahapatra, J. A. Halfen and W. B. Tolman, J. Chem. Soc., Chem. Commun., 1994, 1625 DOI: 10.1039/C39940001625
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