The postulated iron peroxy species involved in acyl–carbon fission by 17α-hydroxylase-17,20-lyase (P-45017α) was trapped by an aldehyde analogue, partial 9, that was cleaved by the enzyme 10 times faster than the side-chain of the natural substrate 1.
P. Robichaud, J. N. Wright and M. Akhtar, J. Chem. Soc., Chem. Commun., 1994, 1501 DOI: 10.1039/C39940001501
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