The unsaturated alcohols derived from a ‘one-pot’ tandem [2,3]-Wittig-anionic oxy-Cope (AOC) rearrangement undergo a halocyclisation reaction with iodine in acetonitrile to give substituted tetrahydropyrans with a high degree of stereocontrol.
N. Greeves and K. J. Vines, J. Chem. Soc., Chem. Commun., 1994, 1469 DOI: 10.1039/C39940001469
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