Catalytic asymmetric hydroalkenylation of norbornene (bicyclo[2.2.1]hept-2-ene) can be performed in 93% e.e. using 1-methyl-2-(ethoxycarbonyl)ethenyl triflate 5 as alkenylation agent and Pd{(R)-binap}2 as chiral catalyst.
F. Ozawa, Y. Kobatake, A. Kubo and T. Hayashi, J. Chem. Soc., Chem. Commun., 1994, 1323 DOI: 10.1039/C39940001323
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