Issue 9, 1994

Control of product selectivity for the epoxidation of allyl alcohol by variation of the acidity of the catalyst TS-1

Abstract

The acidity of TS-1 controls the product selectivity for the epoxidation of allyl alcohol with H2O2; base treatment of TS-1 enhances the selectivity to glycidol whereas incorporation of Brønsted acid sites enhances the selectivity to the products of solvolysis ring opening reactions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1095-1096

Control of product selectivity for the epoxidation of allyl alcohol by variation of the acidity of the catalyst TS-1

G. J. Hutchings and D. F. Lee, J. Chem. Soc., Chem. Commun., 1994, 1095 DOI: 10.1039/C39940001095

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