Catalytic hydrogenation of the title compound proceeds from the site anti to the 7-methyl group to give the cis-dimethyl derivative; a possible stereoelectronic effect accounting for this selectivity is proposed based on the conformational analysis of the substrate by X-ray crystallography.
M. Sato, H. Kuroda, C. Kaneko and T. Furuya, J. Chem. Soc., Chem. Commun., 1994, 687 DOI: 10.1039/C39940000687
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