Reaction of a variety of aldehydes with diketene in the presence of chiral Schiff base–titanium alkoxide complexes proceeds with high enantioselectivity to afford the corresponding 5-hydroxy-3-oxoesters.
M. Hayashi, T. Inoue and N. Oguni, J. Chem. Soc., Chem. Commun., 1994, 341 DOI: 10.1039/C39940000341
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