Diversely protected 2-azido-2-deoxy-D-glycopyranoses are prepared by azido phenylselenylation of the corresponding glycal followed by hydrolysis of the resulting selenoglycosides: from protected D-galactal, protected 2-azido-2-deoxy-D-galactopyranose is obtained, as the sole product in 72% overall yield.
S. Czernecki, E. Ayadi and D. Randriamandimby, J. Chem. Soc., Chem. Commun., 1994, 35 DOI: 10.1039/C39940000035
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