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Issue 10, 1994
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Conformationally restricted Criegee intermediates: evidence for formation and stereoelectronically controlled fragmentation

Abstract

The Baeyer–Villiger reaction of 2-(2-oxocyclohexyl)acetic acid occurs via a bicyclic Criegee intermediate, which fragments with stereoelectronic control, as evidenced by product analysis; the reaction of the-but-2-yl ester and of 2-(2-oxocyclopentyl)acetic acid also show evidence of such stereoelectronic control, but less convincingly.

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Article information


J. Chem. Soc., Perkin Trans. 2, 1994, 2141-2143
Article type
Paper

Conformationally restricted Criegee intermediates: evidence for formation and stereoelectronically controlled fragmentation

S. Chandrasekhar and C. D. Roy, J. Chem. Soc., Perkin Trans. 2, 1994, 2141
DOI: 10.1039/P29940002141

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