cis-Cyclohexa-3,5-diene-1,2-diols 3, which are available by microbial oxidation of aromatic compounds, have been converted into 5-substituted conduritols D 5 by catalytic osmylation:, application of the method to the preparation of homochiral 5-deuteriated conduritol D 2 is described.
H. A. J. Carless, K. Busia, Y. Dove and S. S. Malik, J. Chem. Soc., Perkin Trans. 1, 1993, 2505 DOI: 10.1039/P19930002505
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