Racemic 7-methyljasmonic acid 6 and 7-methyl-7-epi-jasmonic acid 7 have been synthesised. Bioassay of these derivatives for induction of tendril coiling in Bryonia dioica demonstrated that the observed biological activity of jasmonic acid is due to the minor 7-epi-isomer.
J. L. Ward and M. H. Beale, J. Chem. Soc., Perkin Trans. 1, 1993, 2379 DOI: 10.1039/P19930002379
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