The novel title diene 4, prepared from 3,4,6-tri-O-acetyl-D-glucal, is a stable compound which undergoes Diels–Alder reactions with electron-deficient dienophiles, to give cyclohexanone derivatives.
P. Areces, E. Román, M. C. Pozo and J. A. Serrano, J. Chem. Soc., Perkin Trans. 1, 1993, 1939 DOI: 10.1039/P19930001939
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