Issue 7, 1993

2,2-Difluoro enol silyl ethers: convenient preparation and application to the synthesis of a novel fluorinated brassinosteroid

Abstract

On treatment with Grignard reagents, trifluoroacetyltriphenylsilane was converted into 2,2-difluoro enol silyl ethers in almost quantitative yields. As a synthetic application of the 2,2-difluoro enol silyl ether, a novel fluorinated brassinosteroid was synthesized.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1993, 795-799

2,2-Difluoro enol silyl ethers: convenient preparation and application to the synthesis of a novel fluorinated brassinosteroid

F. Jin, Y. Xu and W. Huang, J. Chem. Soc., Perkin Trans. 1, 1993, 795 DOI: 10.1039/P19930000795

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