Irradiation of difluorodiiodomethane 1 with pyrroles, indole and imidazoles in dimethylformamide gives the Corresponding trifluoromethylated products, whereas irradiation with enamines results in 2-trifluoromethyl ketones. A photoinduced electron-transfer mechanism is proposed.
Q. Chen and Z. Li, J. Chem. Soc., Perkin Trans. 1, 1993, 645 DOI: 10.1039/P19930000645
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