SiD2, generated via the laser flash photolysis of phenyl[2H3]silane, has been detected via a ro-vibrational transition in its Ã(1B1)â†� X(1A1) absorption band. It has been monitored for the first time in time-resolved studies to give an absolute rate constant of (3.8 ± 0.2)× 10–12 cm3 molecule–1 s–1 for the reaction SiD2+ H2. Product SiH2 from this reaction was also observed.
B. P. Mason, H. M. Frey and R. Walsh, J. Chem. Soc., Faraday Trans., 1993, 89, 4405 DOI: 10.1039/FT9938904405
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