Adsorption of neopentane on faujasite, mordenite and ZSM-5 zeolites has been investigated by UV–VIS spectroscopy. At room temperature, UV–VIS active surface species were detected and assigned to alkenyl-type carbenium ions. Their formation was shown to be influenced by the overall acidity, the ratio of Brønsted to Lewis acidity and the zeolite structure.
I. Kiricsi, G. Tasi, P. Fejes and H. Förster, J. Chem. Soc., Faraday Trans., 1993, 89, 4221 DOI: 10.1039/FT9938904221
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