Interactions between cations and sugars. Part 7.—Gibbs energies, enthalpies and entropies of association of the trivalent lanthanide cations with ribose in water at 298.15 K

Abstract

Standard Gibbs energies, enthalpies and entropies of association of the trivalent lanthanide cations with the complexing sites of ribose have been determined in water using a calorimetric method and following a procedure that allows the non-specific interactions to be neglected. For the cations going from La³⁺ to Tb³⁺ only 1 : 1 complexes were observed; the stability constants, the values of which range between 3 and 11, show a maximum for Sm³⁺. No significant complexation of the heavier lanthanide cations was detected. The results have been compared with those obtained for stronger ligands also bearing oxygen atoms as coordinating sites, showing that ribose is as selective towards the lanthanide cations as are these stronger ligands. On the other hand, comparison of the entropies of the complexes with those of the free cations has revealed a behaviour change starting with Eu³⁺, thus supporting the controversial assumption of a coordination number change along the lanthanide series.