Issue 7, 1993
From the journal:

Journal of the Chemical Society, Dalton Transactions

Kinetics and mechanism of the substitution of [(NH3)5RuIII(edta)RuIII(H2O)]2+(edta = ethylenediaminetetraacetate) by thiourea in aqueous solution

Debabrata Chatterjee  and  Heri C. Bajaj  

Abstract

The substitution of the H2O ligand of the complex [(NH3)5RuIII(edta)RuIII(H2O)]2+(edta = ethylenediaminetetraacetate) by thiourea was studied spectrophotometrically. Rate and activation parameters are found to be consistent with an associative interchange mechanism. Experimetal results are discussed with reference to literature data for the corresponding substitution of mononuclear [RuIII(edta)(H2O)]–.

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Article information

DOI
https://doi.org/10.1039/DT9930001065
Article type
Paper

J. Chem. Soc., Dalton Trans., 1993, 1065-1067

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Kinetics and mechanism of the substitution of [(NH3)5RuIII(edta)RuIII(H2O)]2+(edta = ethylenediaminetetraacetate) by thiourea in aqueous solution

D. Chatterjee and H. C. Bajaj, J. Chem. Soc., Dalton Trans., 1993, 1065 DOI: 10.1039/DT9930001065

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