Syntheses, spectroscopy and electrochemistry of nitridorhenium(V) organometallics. X-Ray crystal structure of [ReVNMe2(PPh3)2]
Abstract
Treatment of [ReVNCl2(PPh3)2] with LiR gives the complexes [ReVNR2(PPh3)2](R = Me, C
CBut, Ph or C6H4Me-p) which show rich photophysical behaviour; the crystal structure of [ReVNMe2(PPh3)2] exhibits a Re
N distance of 1.641 (4)Å.
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